尹宏峰　研究員

尹宏峰   研究員

新能(néng)源技術研究所（工業催化團隊負責人）

中國(guó)科學(xué)院甯波甯波材料技術與工程研究所                            

地址：浙江省甯波市鎮海區中官西路1219号，315201

手機：13586523816              電話：（0574）86324593

傳真：（0574）86685043   電子郵箱： yinhf@nimte.ac.cn

 

 

尹宏峰，研究員，1999年畢業于南京大學(xué)化學(xué)化工學(xué)院化學(xué)系，獲學(xué)士學(xué)位；2006年獲美國(guó)俄亥俄州立大學(xué)化學(xué)專業博士學(xué)位，師從Malcolm H. Chisholm教授；2007年-2010年在美國(guó)能(néng)源部橡樹嶺國(guó)家實驗室從事(shì)博士後(hòu)研究。2010年9月以“團隊行動”人才計劃引進(jìn)，加入中科院甯波材料所燃料電池事(shì)業部，任研究員，從事(shì)SOFC燃料電池燃料氣體前處理及尾氣後(hòu)處理，電極材料的合成(chéng)及電極表面(miàn)電化學(xué)反應機理研究。2014年7月轉入中科院甯波材料所新能(néng)源技術研究所工業催化團隊，2015年8月擔任團隊負責人，從事(shì)納米材料的合成(chéng)及其在催化反應中的應用與機理研究、鎳基催化劑在燃料電池原料氣重整反應中的催化性能(néng)、抗積碳性能(néng)和反應機理研究，同時還(hái)主持開(kāi)發(fā)合成(chéng)氣制化工産品工業化技術等。已在國(guó)際一流雜志PNAS, ACS Catalysis, Chem. Comm., JPCC., J.Mater.Chem.A，Langmuir等學(xué)術期刊上發(fā)表學(xué)術論文40餘篇，申請或授權發(fā)明專利15項，授權2項。曾在國(guó)家973計劃青年科學(xué)家專題“高效金屬-氧化物複合催化劑的理性設計與性能(néng)調控”中擔任方向(xiàng)負責人。目前承擔國(guó)家自然科學(xué)基金項目和浙江省自然科學(xué)基金項目，甯波市重大專項等。

 

 

主持或參與項目：

1. “高效金屬-氧化物複合催化劑的理性設計與性能(néng)調控”，科技部973計劃青年科學(xué)家專項，方向(xiàng)負責人；

2. “高活性納米複合物(Au-MO_x)@m-SiO₂介孔核殼結構的合成(chéng)及其在高溫氧化中的催化和抗燒結性研究” ，國(guó)家自然科學(xué)基金面(miàn)上項目，主持；

３. 浙江省自然科學(xué)基金，主持

４.“合成(chéng)氣制乙二醇工藝技術開(kāi)發(fā)” ，企業橫向(xiàng)項目，主持　

5. “甘油制1，3-丙二醇催化工藝技術開(kāi)發(fā)”，企業橫向(xiàng)項目，主持　

6. “烯烴高值轉化的高效催化工藝開(kāi)發(fā)”，甯波市“科技創新2025”重大專項，主持。

 

 

發(fā)表文章：

[1] Q. Li, H.B. Yu, K.J. Li, H.F. Yin^*, S.H. Zhou*, “Controlled Synthesis and Enhanced Catalytic Activity of Well-defined Close-contact Pd-ZnO Nanostructures”, Langmuir, accepted.

[2]M.M. Liu, W.Q. Tang, Y.S. Xu, H.B. Yu, H.F. Yin*, S.L. Zhao *, S.H. Zhou *,  “Pd-SnO2/Al2O3 heteroaggregate nanocatalysts for selective hydrogenations of p-nitroacetophenone and p-nitrobenzaldehyde”. Appl. Catal. A-General.  549(2018), 273-279.

[3]K.J. Li, J.X. Wei, H.B. Yu, P.Y. Xu, J.H. Wang, H.F. Yin, Martien A. C. Stuart, J.Y. Wang,* and S.H. Zhou*, “A Generic Method for Preparing Hollow Mesoporous Silica Catalytic Nanoreactors with Metal Oxide Nanoparticles inside Their Cavities”, Angewa. Chemie. Intl. Ed. 57(2018), 50, 16458-16463.

[4]X.Y. Liang, C.Z. Wu, X.L.Yu, W.X. Huang, H.F. Yin*, “Pd Doped La0.1Sr0.9TiO3 as High-Temperature Water-Gas Shift Catalysts: In-Situ Formation of Active Pd Phase”, Catal. Letters, 148(2018), 9, 2830-2838. 

[5]M. Liu, W. Tang, Z. Xie, H. Yu, H. Yin, Y. Xu,* S. Zhao*, S. Zhou*, “Design of Highly Efficient Pt-SnO2 Hydrogenation Nanocatalysts using Pt@Sn Core−Shell Nanoparticles”，ACS Catal. 7(2017), 3, 1583–1591.

[6] X.L. Yu, H.B. Yu, Z. Lim, G.M. Yang, Z.H. Xie, S.H. Zhou, H.F. Yin* “Size-controlled synthesis of thermal stable single-cored Ru@H-SiO₂ core-shell nanoparticles”，Chemical Physics Letters，654 (2016)， 103-106.

[7] Z. Lim, C.Z. Wu, W.G. Wang, K. Choy*, H.F. Yin* “Porosity effect on ZrO₂ hollow shells and hydrothermal stability for catalytic steam reforming of methane” J. Mater. Chem. A, 4(2016), 153–159

[8] Z. Lim, C.Z. Wu, W.G. Wang, K. Choy*, H.F. Yin* “A novel and anti-agglomerating Ni@yolk–ZrO₂ structure with sub-10 nm Ni core for high performance steam reforming of methane” RSC Advances, 5(2015), 61925–61932.

[9] L.J. Hu; C. Zhou; C.Z. Wu; H.F. Yin*; S.H. Zhou and W.G. Wang, “Fe, Pd co-incorporated LaCoO₃ perovskites: modification of thermal stability and catalytic activity for gasoline vehicle exhausts purification.” Eur. J. Inorg. Chem. 13(2015), 2317–2322.

[10]C. Zhou; Y.X. Zhang; L.J. Hu; H.F. Yin*; W.G. Wang, “Synthesis, characterization and catalytic activity of La_0.8Sr_0.2Co_1-xMn_xO₃ (x=0.0, 0.1, 0.3, 0.5) perovskite oxides for three way catalysis.” Chem. Eng. Tech., 38(2015), 291-296.

[11]C. Zhou; Z.J. Feng; Y.X. Zhang; L.J. Hu; R. Chen; B. Shan*; H.F. Yin*; W. Wang; A. Huang, “Enhanced catalytic activity for NO oxidation over Ba doped LaCoO₃ catalyst.” RSC Advances, 5(2015), 28054-28059.

[12]C. Zhou, X. Liu, C.Z. Wu, Y.W. Wen, Y.J. Xue, R. Chen, Z.L. Zhang, B. Shan,* H.F. Yin* ,W.G. Wang, “NO oxidation catalysis on copper doped hexagonal phase LaCoO₃: a combined experimental and theoretical study”Phys.Chem.Chem.Phys.,16(2014) 5106-5112.

[13] C.Z. Wu, Z.Y Lim, C. Zhou, W.G. Wang, S.H. Zhou, H.F. Yin* , Y.J. Zhu，“A Soft-templated method to synthesize Sinteringresistant Au-mesoporous-silica Core-Shell nanocatalysts with Sub-5 nm Single-core， Chem. Comm. 49(2013), 31, 3215-3217.

[14] Y.B. Hu, K. Tao,  C.Z. Wu, C. Zhou, H.F. Yin*, S.H. Zhou*, Size-Controlled Synthesis of Highly Stable and Active Pd@SiO₂ Core-Shell Nanocatalysts for Hydrogenation of Nitrobenzene” J. Phys. Chem. C, 117(2013),17, 8974-8982.

[15] Z.B. Peng, H. Miao, H.F. Yin, C. Xu, W.G. Wang “PEG-assisted Solid State Synthesis and Characterization of Carbon-Coated Li₂MnSiO₄ Cathode Materials for Lithium Ion Battery” Intl. J. Electronchem. Sci., 8(2013) 903-913.

[16] 彭振博，苗鶴，尹宏峰，趙文光，王蔚國(guó)， 噴霧幹燥-高溫固相法合成(chéng)锂離子電池正極材料-Li₂MnSiO₄的研究，材料導報，2012，26(24) 46-49.

[17] H.F. Yin, Z. Ma, M.F. Chi, S. Dai, Heterostructured catalysts prepared by dispersing Au@Fe₂O₃ core-shell structures on supports and their performance in CO oxidation, Catalysis Today 160 (2011) 87-95.

[18] H.F. Yin, Z. Ma, H.G. Zhu, M.F. Chi, S. Dai, Evidence for and mitigation of the encapsulation of gold nanoparticles within SiO₂ matrix upon calcining Au/SiO₂ catalysts at high temperatures: implication to catalyst deactivation, Applied Catalysis A: General 386 (2010) 147-156.

[19] Z. Ma, H.F. Yin, S. Dai, Influence of preparation methods on the performance of metal phosphate-supported gold catalysts in CO oxidation, Catalysis Letters 138 (2010) 40-45.

[20] H.F. Yin, Z. Ma, M.F. Chi, S. Dai, Activation of dodecanethiol-capped gold catalysts for CO oxidation by treatment with KMnO₄ or K₂MnO₄, Catalysis Letters 136 (2010) 209-221.

[21] E.W. Hagaman, J. Jiao, B.H. Chen, Z. Ma, H.F. Yin, S. Dai, Surface alumina species on modified titanium oxide: a solid-state ²⁷Al MAS and 3QMAS NMR investigation of catalyst supports, Solid State Nuclear Magnetic Resonance 37 (2010) 82-90.

[22] Z. Ma, H.F. Yin, S. Dai, Performance of Au/M_xO_y/TiO₂ catalysts in water-gas shift reaction, Catalysis Letters 136 (2010) 83-91.

[23] W. Dmowski , H.F. Yin, S. Dai, S.H. Overbury , T. Egami, Atomic Structure of Au Nanoparticles on a Silica Support by an X-ray PDF Study” Journal of Physical Chemistry C, 114(2010), 6983-6988.

[24] J.N. Zhang, Z. Ma, J. Jiao, H.F. Yin, W.F. Yan, E.W. Hagaman, J.H. Yu, S. Dai Surface functionalization of mesoporous silica SBA-15 by liquid-phase grafting of zirconium phosphate. Microporous Mesoporous Materials 129(2010), 200-209.

[25] C. Wang, H.F. Yin, S. Dai, S.H. Sun, A General Approach to Noble Metal-Metal Oxide Dumbbell Nanoparticles and Their Catalytic Application for CO Oxidation”, Chemistry of Materials, 22(2010), 3277-3282.

[26] C. Bouvy, G.A. Baker, H.F. Yin, S. Dai. Growth of Gold Nanosheets and Nanopolyhedra in Pyrrolidinium-Based Ionic Liquids: Investigation of the Cation Effect on the Resulting Morphologies. Crystal Growth & Design 10(2010), 1319-1322.

[27] J.N. Zhang, Z. Ma, J. Jiao, H.F. Yin, W.F. Yan, E.W. Hagaman, J.H. Yu, S. Dai, Layer-by-layer grafting of titanium phosphate onto mesoporous silica SBA-15 surfaces: synthesis, characterization, and applications, Langmuir 25 (2009) 12541-12549.

[28] S.H. Zhou, Z. Ma, H.F. Yin, Z.L. Wu, B. Eichhorn, S.H. Overbury, S. Dai, Low-temperature solution-phase synthesis of NiAu alloy nanoparticles via butyllithium reduction: influences of synthesis details and application as the precursor to active Au-NiO/SiO₂ catalysts through proper pretreatment, Journal of Physical Chemistry C 113 (2009) 5758-5765.

[29] C. Wang, H.F. Yin, R. Chan, S. Peng, S. Dai, S.H. Sun, One-Pot Synthesis of Oleylamine Coated AuAg Alloy NPs and Their Catalysis for CO Oxidation, Chemistry of Materials, 21(2009), 433-435.

[30] S. Peng, Y.M. Lee, C. Wang, H.F. Yin, S. Dai, S.H. Sun, A Facile Synthesis of Monodisperse Au Nanoparticles and Their Catalysis of CO Oxidation, Nano Research, 1(2008), 229-234.

[31] Z. Ma, H.F. Yin, S.H. Overbury, S. Dai, Metal phosphates as a new class of supports for gold nanocatalysts, Catalysis Letters 126 (2008) 20-30.

[32] S.H. Zhou, H.F. Yin, V. Schwartz, Z.L. Wu, D. Mullins, B. Eichhorn, S.H. Overbury, S. Dai. In Situ Phase Separation of NiAu Alloy Nanoparticles for Preparing Highly Active Au/NiO CO Oxidation Catalysts. ChemPhysChem 9(2008), 2475-2479.

[33] H.F. Yin, Z. Ma, S.H. Overbury, S. Dai, Promotion of Au(en)₂Cl₃-derived Au/fumed SiO₂ by treatment with KMnO₄, Journal of Physical Chemistry C 112 (2008) 8349-8358.

[34] H.F. Yin, C. Wang, H.G. Zhu, S.H. Overbury, S.H, Sun, S. Dai, Colloidal deposition synthesis of supported gold nanocatalysts based on Au-Fe3O4 dumbbell nanoparticles, Chemical Communications, 36(2008), 4357-4359

[35]  M.H. Chisholm, J.C. Gallucci, H.F. Yin. 18-Membered cyclic esters derived from glycolide and lactide: preparations, structures and coordination to sodium ions, Dalton Transactions, 2007, 4811-4821.

[36]  M.H. Chisholm, J.C. Gallucci, H.F. Yin. Cyclic-Esters and Cyclodepsipeptides Derived from Lactide and 2,5-Morpholinediones. Proceedings of National Academy of Science. U. S. A. (103)2006, 103, 15315-15320.

[37]  M.H. Chisholm, J.C. Gallucci, H.F. Yin, H.S. Zhen, Hongshi.  Arylzinc Alkoxides: [ArZnOCHPrⁱ₂]₂ and Ar₂Zn₃(OCHPrⁱ₂)₄ When Ar = C₆H₅, p-CF₃C₆H₄, 2,4,6-Me₃C₆H₂, and C₆F₅. Inorganic Chemistry 44(2005), 4777-4785.

[38] G. Li, F.F Zhang, H. Chen, H.F. Yin, H.L. Chen, S.Y. Zhang.   Determination of Co-C bond dissociation energies for organocobalt complexes related to coenzyme B12 using photoacoustic calorimetry. J. Chem. Soc, Dalton Transactions 2002, 105-110.

[39] F.F Zhang, G. Li, H.F. Yin, S.Y. Zhang, H.L. Chen. Photoacoustic studies on radical kinetics and enthalpy change for photolysis of methylcobalamin. Progress in Natural Science (11)2001, S330-S333.

[40] G. Li, F.F Zhang, H. Chen, H.F. Yin, H.L. Chen, S.Y. Zhang. Using time-resolved photoacoustic calorimetry to study triplet energy and lifetime for benzophenone-KI system. Chinese. Science Bulletin  45(2000), 45, 335-338.

[41] F.F Zhang, G. Li, H.F. Yin, H.L. Chen, S.Y. Zhang. Determination of Co-C bond dissociation energy for n-C₄H₉Co(Salen)H₂O using photoacoustic calorimetry. Chinese Journal of Inorganic Chemistry 16(2000), 144-146.

 

申請專利：

[1]餘小龍，尹宏峰，于洪波。用于加氫合成(chéng)對(duì)氯苯胺反應的催化劑、其制備方法及應用。申請号：CN201610129732.X。公告号：CN105562032A，已授權。

[2]薛業建，王蔚國(guó)，尹宏峰，周陳。一種(zhǒng)高性能(néng)低成(chéng)本三元催化劑的制備方法。專利号：201110298424.7，已授權。

[3]許傑、尹宏峰。一種(zhǒng)工業萘生産的精萘方法。申請号：201810201981.4

[4]尹宏峰、許傑。工業萘選擇性加氫催化劑及其制備方法。申請号：201810201966.X。

[5]許傑、尹宏峰。一種(zhǒng)精萘的生産方法。申請号：201810201980.X。

[6]許傑、尹宏峰。工業萘選擇性加氫催化劑、其制備方法與應用。申請号：201810201419.1。

[7]尹宏峰、許傑。工業萘選擇性加氫催化劑載體及其制備方法。申請号：201810201431.2。

[8]梁蕭雅，尹宏峰，餘小龍。M_y/La_xSr_1-xTi_1-yO₃催化劑、其制法及應用。申請号：201810049803.4。

[9]席盼盼; 尹宏峰。一種(zhǒng)可控的雙金屬核殼納米結構、催化劑、其制法與應用。申請号：201810244656.6。

[10]尹宏峰，許傑。 一種(zhǒng)加氫裂化催化劑及其制備方法與應用。申請号：201710629122.0。

[11]許傑、尹宏峰。 劣質油料的加氫處理催化劑及其制備方法與應用。申請号： 201710629137.7。

[12]尹宏峰、許傑。 一種(zhǒng)加氫裂化催化劑及其制備方法與應用。申請号： 201710629122.0。

[13]尹宏峰、許傑。 處理劣質油料的加氫精制催化劑及其制備方法與應用。申請号： 201710629136.2。

[14]尹宏峰、許傑。一種(zhǒng)加氫精制催化劑及其制備方法與應用。申請号：201710629489.2。

[15]許傑,尹宏峰。劣質油料生産柴油的方法及系統。申請号：201510581854.8。

 

國(guó)際會議論文：

1. H.F. Yin*, C.Z Wu, S.H. Zhou, W.G. Wang, Several Approaches to Prepare Stable and Active Gold Nanocatalysts, 2^nd Annual World Congress of Advanced Materials, 2013, Suzhou, China
2. 尹宏峰，負載型Au@Fe₂O₃核殼納米催化劑的合成(chéng)及其在一氧化碳氧化催化中的性能(néng)，第十六屆全國(guó)催化會議，2012，沈陽
3. Yin, Hongfeng; Overbury, Steve H.; Dai, Sheng “Oxidative removal of organic surfactant and promotion of Au/support (support=SiO₂, TiO₂, carbon) by treatment with K₂MnO₄ and KMnO₄.” 238^th ACS Fall Meeting, 2009, Washington, D.C. (Oral presentation)
4. Chisholm, Malcolm H.; Gallucci, Judith C.; Yin, Hongfeng; Zhen, Hongshi, “Arylzinc Alkoxides: [ArZnOCHPrⁱ₂]₂ and Ar₂Zn₃(OCHPrⁱ₂)₄ When Ar = C₆H₅, p-CF₃C₆H₄, 2,4,6-Me₃C₆H₂, and C₆F₅.” Abstr. Pap. Am. Chem. Soc. 2003, 225, U126-U126.
5. Yin, Hongfeng; Yan, Wenfu; Dai, Sheng “Rapid Modification of TiO₂ Surface with Highly Conformal Multi-Layer Silicon Oxide via Surface Sol-Gel Process” MRS 2007 Fall Meeting, 2007, Boston.
6. Yin, Hongfeng, Xu Wei, Zhou Shenghu “Synthesis and characterization of doped mesoporous W-FDU-12 with large pores: An enhanced catalyst for metathesis of ethene and 1-butene to propene”，252th ACS Fall Meeting, Philadelphia, PA, U.S.A, Aug., 2016(Oral presentation). 
7. Yin, Hongfeng, Yu Xiaolong”Size-controlled synthesis of thermal stable Ru@H-SiO₂ core-shell nanoparticles and their catalytic applications”252th ACS Fall Meeting, Philadelphia, PA, U.S.A, Aug., 2016(Oral presentation)